Your P60 Explained
A P60 is a certificate your employer must give you by 31 May each year, summarising your total pay and deductions for the tax year that just ended (6 April to 5 April). If you only had one job all year, it's essentially a year-end receipt for everything that came off your pay. See Your Payslip Explained for what the same figures look like on the document you actually see every pay period, not just once a year. Keep it safe. You'll need it if you ever have to prove your income, apply for a mortgage, or check whether you've been correctly taxed. HMRC recommends keeping P60s for at least six years.
HMRC does its own version of that "correctly taxed" check too, separately. If the numbers don't match what you should have paid, they'll tell you via a P800.
If you've recently changed jobs, you might also want to see Your P45 Explained, the certificate your previous employer would have given you when you left, covering the part of the tax year you worked for them.